The following example demonstrates how to enter edit mode only when a cell becomes current by setting the EditTriggers property to CellIsCurrent.

XAML
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<Grid xmlns:xcdg="http://schemas.xceed.com/wpf/xaml/datagrid">

  <Grid.Resources>

    <xcdg:DataGridCollectionViewSource x:Key="cvs_orders"

                                    Source="{Binding Source={x:Static Application.Current},

                                     Path=Orders}"/>

  </Grid.Resources>

  <xcdg:DataGridControl x:Name="OrdersGrid"

                        ItemsSource="{Binding Source={StaticResource cvs_orders}}"

                        EditTriggers="CellIsCurrent"/>      

</Grid>